2-氯吡啶氮氧化物的合成方法研究Study on the Synthesis of 2-chloropyridine-N-oxide
郑淑玲;赵增国;张红艳;
摘要(Abstract)：
对以2-氯吡啶为原料、双氧水为氧化剂、钨酸和硫酸为催化剂合成2-氯吡啶-N-氧化物的方法进行了反复实验.该方法的最佳反应条件为:催化剂浓H2SO4与2-氯吡啶的体积分数为0.2∶1.0~0.3∶1.0,2-氯吡啶与钨酸的物质的量比为18.5∶1~20.8∶1,反应中H2O2与2-氯吡啶的物质的量比为1.3∶1~1.5∶1,反应最适温度为70~80℃,满足这些条件的反应产率为90%以上.
关键词(KeyWords)： 2-氯吡啶;硫酸;钨酸;2-氯吡啶-N-氧化物
基金项目(Foundation): 国家“八五”重大科技攻关项目的下游系列产品的研究项目(85-504-21-01)
作者(Author): 郑淑玲;赵增国;张红艳;
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DOI:
参考文献(References)：
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