锂硫二次电池研究进展Research progress in lithium-sulfur secondary batteries
张波;刘晓晨;李德军;
摘要(Abstract):
锂硫电池具有理论比容量高、价格低廉、环境友好等性质,是一种高性能的新型储能电池,在电动汽车及电子设备领域具有重要意义.然而,库伦效率低、循环性能差等问题导致锂硫电池还不能达到商业化应用的要求.本文从正极材料设计、电解液体系的优化、固态电解质的采用以及锂负极保护等方面全面总结了锂硫电池的最新研究进展,并对锂硫电池未来的发展方向进行展望.
关键词(KeyWords): 锂硫电池;正极材料;固态电解质;锂负极保护
基金项目(Foundation): 天津师范大学人才引进资助项目(011/5RL132)
作者(Author): 张波;刘晓晨;李德军;
Email:
DOI: 10.19638/j.issn1671-1114.20200101
参考文献(References):
- [1]辛森,郭玉国,万立骏.高能量密度锂二次电池电极材料研究进展[J].中国科学:化学,2011,41(8):1229-1239.XIN S,GUO Y G,WAN L J.Electrode materials for lithium secondary batteries with high energy densities[J].Scientia Sinica:Chimica,2011,41(8):1229-1239(in Chinese).
- [2]LI Q,ZHANG Z,GUO Z,et al.Improved cyclability of lithium-sulfur battery cathode using encapsulated sulfur in hollow carbon nanofiber@nitrogen-doped porous carbon core-shell composite[J].Carbon,2014,78:1-9.
- [3]ZHANG S S.Liquid electrolyte lithium/sulfur battery:Fundamental chemistry problems and solutions[J].Journal of Power Sources,2013,231:153-162.
- [4]REDDY M V,SUBBA RAO G V,CHOWDARI B V R.Metal oxides and oxysalts as anode materials for Li ion batteries[J].Chemical Reviews,2013,113(7):5364-5457.
- [5]DIAO Y,XIE K,XIONG S Z,et al.Shuttle phenomenon-The irreversible oxidation mechanism of sulfur active material in Li-S battery[J].Journal of Power Sources,2013,235:181-186.
- [6]JAYAPRAKASH N,SHEN J,MOGANTY S S,et al.Porous hollow carbon@sulfur composites for high-power lithium-sulfur batteries[J].Angewandte Chemie International Edition,2011,50(26):5904-5908.
- [7]ZHANG B,ZHAO Y M,LIU J,et al.Impact of micro-/mesoporous carbonaceous structure on electrochemical performance of sulfur[J].Electrochimica Acta,2017,248:416-424.
- [8]LIANG C D,DUDNEY N J,HOWE J Y.Hierarchically structured sulfur/carbon nanocomposite material for high-energy lithium battery[J].Chemistry of Materials,2009,21(19):4724-4730.
- [9]ZHANG B,QIN X,LI G R,et al.Enhancement of long stability of sulfur cathode by encapsulating sulfur into micropores of carbon spheres[J].Energy&Environmental Science,2010,3(10):1531-1537.
- [10]XIN S,GU L,ZHAO N H,et al.Smaller sulfur molecules promise better lithium-sulfur batteries[J].Journal of the American Chemical Society,2012,134(45):18510-18513.
- [11]WU H B,WEI S Y,ZHANG L,et al.Embedding sulfur in MOF-derived microporous carbon polyhedrons for lithium-sulfur batteries[J].Chemistry,2013,19(33):10804-10808.
- [12]PARK M S,JEONG B O,KIM T J,et al.Disordered mesoporous carbon as polysulfide reservoir for improved cyclic performance of lithiumsulfur batteries[J].Carbon,2014,68:265-272.
- [13]ZHANG B,LAI C,ZHOU Z,et al.Preparation and electrochemical properties of sulfur-acetylene black composites as cathode materials[J].Electrochimica Acta,2009,54(14):3708-3713.
- [14]LI X L,CAO Y L,QI W,et al.Optimization of mesoporous carbon structures for lithium-sulfur battery applications[J].Journal of Materials Chemistry,2011,21(41):16603-16610.
- [15]CHEN S R,ZHAI Y P,XU G L,et al.Ordered mesoporous carbon/sulfur nanocomposite of high performances as cathode for lithium-sulfur battery[J].Electrochimica Acta,2011,56(26):9549-9555.
- [16]HE J R,CHEN Y F,LYU W,et al.From Metal-organic framework to Li2S@C-Co-N nanoporous architecture:A high-capacity cathode for lithium-sulfur batteries[J].ACS Nano,2016,10(12):10981-10987.
- [17]HE G,JI X L,NAZAR L.High“C”rate Li-S cathodes:Sulfur imbibed bimodal porous carbons[J].Energy&Environmental Science,2011,4(8):2878-2883.
- [18]STRUBEL P,THIEME S,BIEMELT T,et al.ZnO hard templating for synthesis of hierarchical porous carbons with tailored porosity and high performance in lithium-sulfur battery[J].Advanced Functional Materials,2015,25(2):287-297.
- [19]ZHU P Y,SONG J X,LYU D,et al.Mechanism of enhanced carbon cathode performance by nitrogen doping in lithium-sulfur battery:An X-ray absorption spectroscopic study[J].The Journal of Physical Chemistry C,2014,118(15):7765-7771.
- [20]GUO Z J,ZHANG B,LI D J,et al.A mixed microporous/low-range mesoporous composite with high sulfur loading from hierarchicallystructured carbon for lithium sulfur batteries[J].Electrochimica Acta,2017,230:181-188.
- [21]WANG H L,YANG Y Y,LIANG Y,et al.Graphene-wrapped sulfur particles as a rechargeable lithium-sulfur battery cathode material with high capacity and cycling stability[J].Nano Letters,2011,11(7):2644-2647.
- [22]GAO X F,LI J Y,GUAN D S,et al.A scalable graphene sulfur composite synthesis for rechargeable lithium batteries with good capacity and excellent columbic efficiency[J].ACS Applied Materials&Interfaces,2014,6(6):4154-4159.
- [23]TANG C,LI B Q,ZHANG Q,et al.Lithium-sulfur batteries:CaO-templated growth of hierarchical porous graphene for high-power lithiumsulfur battery applications[J].Advanced Functional Materials,2016,26(4):577-585.
- [24]FANG R P,ZHAO S Y,PEI S F,et al.Toward more reliable lithiumsulfur batteries:An all-graphene cathode structure[J].ACS Nano,2016,10(9):8676-8682.
- [25]WANG C,SU K,WAN W,et al.High sulfur loading composite wrapped by 3D nitrogen-doped graphene as a cathode material for lithiumsulfur batteries[J].J Mater Chem A,2014,2(14):5018-5023.
- [26]QIU Y C,LI W F,ZHAO W,et al.High-rate ultralong cycle-life lithium/sulfur batteries enabled by nitrogen-doped graphene[J].Nano Letters,2014,14(8):4821-4827.
- [27]ZHAO M Q,ZHANG Q,HUANG J Q,et al.Unstacked double-layer templated graphene for high-rate lithium-sulphur batteries[J].Nature Communications,2014,5:3410.
- [28]HAN S C,SONG M S,LEE H,et al.Effect of multiwalled carbon nanotubes on electrochemical properties of lithium/sulfur rechargeable batteries[J].Journal of the Electrochemical Society,2003,150(7):A889-A893.
- [29]YIN L C,WANG J L,YANG J,et al.A novel pyrolyzed polyacrylonitrile-sulfur@MWCNT composite cathode material for high-rate rechargeable lithium/sulfur batteries[J].Journal of Materials Chemistry,2011,21(19):6807-6810.
- [30]PENG H J,HOU T Z,ZHANG Q,et al.Strongly coupled interfaces between a heterogeneous carbon host and a sulfur-containing guest for highly stable lithium-sulfur batteries:Mechanistic insight into capacity degradation[J].Advanced Materials Interfaces,2014,1(7):1400227.
- [31]CHANG Z,DOU H,DING B,et al.Interconnected core-shell pyrolyzed polyacrylonitrile@sulfur/carbon nanocomposites for rechargeable lithiumsulfur batteries[J].New Journal of Chemistry,2016,40(9):7680-7686.
- [32]ZHANG L,DU W Y,NAUTIYAL A,et al.Recent progress on nanostructured conducting polymers and composites:Synthesis,application and future aspects[J].Science China Materials,2018,61(3):303-352.
- [33]SEH Z W,LI W Y,CHA J J,et al.Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries[J].Nature Communications,2013,4:1-6.
- [34]WEI H,RODRIGUEZ E F,BEST A S,et al.Chemical bonding and physical trapping of sulfur in mesoporous magnéli Ti4O7 microspheres for high-performance Li-S battery[J].Advanced Energy Materials,2017,7(4):1-10.
- [35]LIANG K,MARCUS K,ZHANG S F,et al.NiS2/FeS holey film as freestanding electrode for high-performance lithium battery[J].Advanced Energy Materials,2017,7(22):1701309.
- [36]HAN S C,KIM K W,AHN H J,et al.Charge-discharge mechanism of mechanically alloyed NiS used as a cathode in rechargeable lithium batteries[J].Journal of Alloys and Compounds,2003,361(1/2):247-251.
- [37]ZHANG S S.Role of LiNO3 in rechargeable lithium/sulfur battery[J].Electrochimica Acta,2012,70:344-348.
- [38]LIN Z,LIU Z C,FU W J,et al.Phosphorous pentasulfide as a novel additive for high-performance lithium-sulfur batteries[J].Advanced Functional Materials,2013,23(8):1064-1069.
- [39]XU Z X,WANG J L,YANG J,et al.Enhanced performance of a lithiumsulfur battery using a carbonate-based electrolyte[J].Angewandte Chemie International Edition,2016,55(35):10372-10375.
- [40]KIM H M,HWANG J Y,AURBACH D,et al.Electrochemical properties of sulfurized-polyacrylonitrile cathode for lithium-sulfur batteries:Effect of polyacrylic acid binder and fluoroethylene carbonate additive[J].The Journal of Physical Chemistry Letters,2017,8(21):5331-5337.
- [41]JEDDI K,GHAZNAVI M,CHEN P.A novel polymer electrolyte to improve the cycle life of high performance lithium-sulfur batteries[J].Journal of Materials Chemistry A,2013,1(8):2769-2772.
- [42]FISHER A S,KHALID M B,WIDSTROM M,et al.Solid polymer electrolytes with sulfur based ionic liquid for lithium batteries[J].Journal of Power Sources,2011,196(22):9767-9773.
- [43]HASSOUN J,SCROSATI B.Moving to a solid-state configuration:Avalid approach to making lithium-sulfur batteries viable for practical applications[J].Advanced Materials,2010,22(45):5198-5201.
- [44]DIETRICH C,WEBER D A,SEDLMAIER S J,et al.Lithium ion conductivity in Li2S-P2S5 glasses-building units and local structure evolution during the crystallization of superionic conductors Li3PS4,Li7P3S11and Li4P2S7[J].Journal of Materials Chemistry A,2017,5(34):18111-18119.
- [45]YAMANE H,SHIBATA M,SHIMANE Y,et al.Crystal structure of a superionic conductor,Li7P3S11[J].Solid State Ionics,2007,178(15/16/17/18):1163-1167.
- [46]XU R C,XIA X H,WANG X L,et al.Tailored Li2S-P2S5 glass-ceramic electrolyte by MoS2 doping,possessing high ionic conductivity for allsolid-state lithium-sulfur batteries[J].Journal of Materials Chemistry A,2017,5(6):2829-2834.
- [47]KAMAYA N,HOMMA K,YAMAKAWA Y,et al.A lithium superionic conductor[J].Nature Materials,2011,10(9):682-686.
- [48]BRON P,JOHANSSON S,ZICK K,et al.Li10SnP2S12:An affordable lithium superionic conductor[J].Journal of the American Chemical Society,2013,135(42):15694-15697.
- [49]KATO Y,HORI S,SAITO T,et al.High-power all-solid-state batteries using sulfide superionic conductors[J].Nature Energy,2016,1(4):16030.
- [50]HAN Q G,LI X L,SHI X X,et al.Outstanding cycle stability and rate capabilities of the all-solid-state Li-S battery with a Li7P3S11glassceramic electrolyte and a core-shell S@BP2000 nanocomposite[J].Journal of Materials Chemistry A,2019,7(8):3895-3902.
- [51]MINAMI K,MIZUNO F,HAYASHI A,et al.Lithium ion conductivity of the Li2S-P2S5 glass-based electrolytes prepared by the melt quenching method[J].Solid State Ionics,2007,178(11/12):837-841.
- [52]AGOSTINI M,AIHARA Y,YAMADA T,et al.A lithium-sulfur battery using a solid,glass-type P2S5-Li2S electrolyte[J].Solid State Ionics,2013,244:48-51.
- [53]NAGATA H,CHIKUSA Y.Activation of sulfur active material in an allsolid-state lithium-sulfur battery[J].Journal of Power Sources,2014,263:141-144.
- [54]TATSUMISAGO M,NAGAO M,HAYASHI A.Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries[J].Journal of Asian Ceramic Societies,2013,1(1):17-25.
- [55]MIZUNO F,HAYASHI A,TADANAGA K,et al.New,highly ionconductive crystals precipitated from Li2S-P2S5 glasses[J].Advanced Materials,2005,17(7):918-921.
- [56]LIU Z C,FU W J,PAYZANT E A,et al.Anomalous high ionic conductivity of nanoporousβ-Li3PS4[J].Journal of the American Chemical Society,2013,135(3):975-978.
- [57]YAMAMOTO H,MACHIDA N,SHIGEMATSU T.A mixed-former effect on lithium-ion conductivities of the Li2S-GeS2-P2S5 amorphous materials prepared by a high-energy ball-milling process[J].Solid State Ionics,2004,175(1/2/3/4):707-711.
- [58]HASSOUN J,VERRELLI R,REALE P,et al.A structural,spectroscopic and electrochemical study of a lithium ion conducting Li10GeP2S12solid electrolyte[J].Journal of Power Sources,2013,229:117-122.
- [59]TREVEY J E,JUNG Y S,LEE S H.High lithium ion conducting Li2S-GeS2-P2S5 glass-eramic solid electrolyte with sulfur additive for all solidstate lithium secondary batteries[J].Electrochimica Acta,2011,56(11):4243-4247.
- [60]LEE Y M,CHOI N S,PARK J H,et al.Electrochemical performance of Lithium/sulfur batteries with protected Li anodes[J].Journal of Power Sources,2003,119:964-972.
- [61]KIZILASLAN A,AKBULUT H.Assembling all-solid-state lithiumsulfur batteries with Li3N-protected anodes[J].ChemPlusChem,2019,84(2):183-189.